Thio derivatives of β-diketones and their metal chelates. XX. Magnetic moments of some ruthenium(III) chelates of fluorinated Monothio-β-diketones
- 1 January 1975
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 28 (11)
- https://doi.org/10.1071/ch9752531
Abstract
Magnetic data have been obtained for ruthenium(III) chelates of the fluorinated monothio-β-diketones RC(SH)=CHCOCF3 (R = 2-thienyl, β- naphthyl, Ph,p-MeC6H4, m-MeC6H4, m-ClC6H4, m-BrC6H4).The compounds are low-spin (S = 1/2) with moments in the range 1.68-1.84 B.M. at room temperature; the moments decrease with decrease in temperature.Keywords
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