On the trapping of sulphenic acids from penicillin sulphoxides
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 24,p. 1683-1684
- https://doi.org/10.1039/c29700001683
Abstract
The intermediate sulphenic acids produced thermally from penicillin sulphoxides can be trapped either intramolecularly, as in the rearrangement of the 2β-acetoxymethyl derivatives into the 2α-acetoxymethyl isomers, or intermolecularly with norbornadiene or dihydropyran.Keywords
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