Photometric studies in hydrogen + oxygen + carbon dioxide flames. Part 1.—Metal hydroxide dissociation energies
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 67, 740-749
- https://doi.org/10.1039/tf9716700740
Abstract
H2+ O2+ CO2 flames offer significant advantages over H2+ O2+ N2 flames as a medium for studying high temperature reactions between metal atoms and oxygen-containing flame gas molecules. The system permits second as well as third law determinations of the bond dissociation energies, D°0(M–OH), of all the molecules GaOH(434 ± 8 kJ mol–1), InOH(374 ± 8), TlOH(< 300), LiOH (433 ± 8), NaOH (330 ± 8), KOH (352 ± 10) and RbOH (362 ± 12). The results are consistent with a linar structure for all these hydroxides.Keywords
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