Zintl Phases: Transitions between Metallic and Ionic Bonding
- 1 September 1973
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 12 (9) , 694-712
- https://doi.org/10.1002/anie.197306941
Abstract
Experimental studies on compounds of alkali and alkaline earth metals with semi‐ and metametals have considerably broadened the basis for a discussion of the transition from metallic to ionic bonding. Current interest is focused mainly upon the elucidation of the principles governing the structure of such compounds which are subject to a wide range of variation within this class of materials. A new definition of the term Zintl phase is proposed after consideration of available findings.Keywords
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