Mercurial derivatives from the reactions of substituted hydrazones with mercury(II) acetate and phenylmercury(II) hydroxide
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 9,p. 986-989
- https://doi.org/10.1039/p19760000986
Abstract
Oxidation of aromatic aldehyde p-tolylsulphonylhydrazones with mercury(II) acetate gave NN″-mercuriobis-(N′-arylmethylenetoluene-p-sulphonohydrazide)s. Treatment of aromatic aldehyde 4-nitrophenylhydrazones with mercury(II) acetate resulted in acetoxymercuriation at the 2-position of the 4-nitrophenyl ring. Treatment of both types of hydrazone with phenylmercury(II) hydroxide gave N-phenylmercurio-derivatives.Keywords
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