Hydroformylation of glucal derivatives with rhodium catalysts. Crucial influence of the auxiliary ligand tris(ortho-tert-butylphenyl) phosphite
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 639-640
- https://doi.org/10.1039/c39920000639
Abstract
Rhodium catalyst mediated hydroformylation of glucal derivatives has been achieved for the first time in good yields and selectivies using [Rh2{µ-S(CH2)3NMe2}2(cycloocta-1,5-diene)2] and tris(ortho-tert-butylphenyl) phosphite as auxiliary ligand giving, principally, 2-formyl derivatives.Keywords
This publication has 0 references indexed in Scilit: