Chemie der Nitrosamine, IV. Synthesen von α‐C‐funktionellen N‐Nitrosodialkylaminen: Ester und Ether von 1‐[(Alkyl)(nitroso)amino]alkoholen
- 10 August 1984
- journal article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 1984 (8) , 1468-1493
- https://doi.org/10.1002/jlac.198419840808
Abstract
Imine (Schiff‐Basen) addieren Nitrosylchlorid unter Bildung von N‐Alkyl‐1‐chlor‐N‐nitrosoalkyl‐aminen 13. Durch nucleophile Substitution mit Acetat oder p‐Nitrobenzoat sind daraus die Acetate 7 und 9 sowie die p‐Nitrobenzoate 8 und 10 zugänglich. Die spektroskopischen Daten und die chemischen Eigenschaften der neu dargestellten Verbindungen werden diskutiert.Keywords
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