Versatile enantiocontrolled synthesis of (+)-fostriecinElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b2/b209742g/
- 15 November 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 3042-3043
- https://doi.org/10.1039/b209742g
Abstract
Fostriecin, a potent protein phosphatase inhibitor and antitumor agent, has been enantioselectively synthesized in naturally occurring form via a versatile route, which also allows one to secure all possible stereoisomeres of the C1–C13 fragment including the C11 stereocenter and the geometry of the Δ12-double bond.Keywords
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