Phosphine complexes of main group elements. A bis-phosphinomethyl lithiate as an anionic diphosphine ligand to lithium: synthesis and structure of {[Me2N(CH2)2NMe2]Li[(Me2P)C(SiMe3)2]2Li}
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 1033-1034
- https://doi.org/10.1039/c39870001033
Abstract
A novel type of Li complexation has been established by X-ray crystallography for the title compound revealing two distinctly different Li atoms, whereas the related compelxes {(thf)Li[(Me2P)2CX]}2(X = SiMe3, PMe2·, thf = tetrahydrofuran) feature equivalent environments for both lithium atoms.Keywords
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