REGIOSELECTIVE SYNTHESIS OF 1-OLEFINS BY PALLADIUM-CATALYZED HYDROGENOLYSIS OF TERMINAL ALLYLIC COMPOUNDS WITH AMMONIUM FORMATE
- 5 June 1984
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 13 (6) , 1017-1020
- https://doi.org/10.1246/cl.1984.1017
Abstract
Various terminal allylic compounds such as allylic esters, phenyl ethers, carbonates, chlorides, and vinyl epoxides react with ammonium or sodium formate to give 1-olefins with high regioselectivity by using palladium–tributylphosphine complex as a catalyst. The reaction offers a useful synthetic method for 1-olefins.This publication has 7 references indexed in Scilit:
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