Studies of Hydrogen Bonding. Part II. Intermolecular Hydrogen Bond Association between Organophosphorus Compounds and Methanol, a-Naphthol and Pentachlorophenol, respectively.

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Abstract
The Kass, [DELTA]H, [DELTA]F and [DELTA]S values of the equilibrium reaction between sixteen organophosphorus compounds and methanol, [alpha]-1 naphthol and pentachlorophenol, respectively, have been determined. It has been found that for each system the [DELTA]H, [DELTA]F and [DELTA]S values form linear relationships with the hydrogen bond frequency shift. The effect of solvent interaction on the hydrogen bond association is considered.