COPPER(I) IODIDE ASSISTED REACTION OF NONACTIVATED IODOARENES WITH SODIUM TRIFLUOROACETATE IN HEXAMETHYLPHOSPHORIC TRIAMIDE. NUCLEAR TRIFLUOROMETHYLATION AND DIARYL ETHER FORMATION

5 January 1982

journal article
research article
Published by Oxford University Press (OUP) in Chemistry Letters

Vol. 11 (1) , 135-136
https://doi.org/10.1246/cl.1982.135

Abstract

Polymethyliodobenzenes react with sodium trifluoroacetate, in tine presence of copper(I) iodide, in hexamethylphosphoric triamide at 150–180°C, giving a mixture of the corresponding polymethylbenzotrifluoride, parent hydrocarbon, and bis(polymethylphenyl) ether.

Keywords

COPPER
ETHER
IODIDE ASSISTED
ASSISTED REACTION
SODIUM TRIFLUOROACETATE
TRIFLUOROMETHYLATION
HEXAMETHYLPHOSPHORIC TRIAMIDE
NONACTIVATED IODOARENES

This publication has 1 reference indexed in Scilit:

The Copper(I) Iodide-assisted Reaction of Nonactivated Aryl Iodides with Some Alkali Metal Pseudohalides
Bulletin of the Chemical Society of Japan, 1980