A Conjugate Addition of Allylsilanes to α,β-Unsaturated Ketones Catalyzed by Trityl Perchlorate
- 5 February 1987
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 16 (2) , 289-292
- https://doi.org/10.1246/cl.1987.289
Abstract
A conjugate addition of allylsilanes to α,β-unsaturated ketones was effectively promoted by a catalytic amount of trityl perchlorate to give the corresponding Michael adducts in good yields.Keywords
This publication has 2 references indexed in Scilit:
- A general allylation procedure using trimethylallylsilane and fluoride catalysisThe Journal of Organic Chemistry, 1986
- Chemistry of organosilicon compounds. 99. Conjugate addition of allylsilanes to .alpha.,.beta.-enones. A New method of stereoselective introduction of the angular allyl group in fused cyclic .alpha.,.beta.-enonesJournal of the American Chemical Society, 1977