A Bridgehead Carbocation Fragmentation Leading to the Taxane AB Ring System
- 1 January 1993
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1993 (01) , 71-72
- https://doi.org/10.1055/s-1993-22353
Abstract
The AB ring system was constructed from cyclohexane-1,3-diones by a direct route. The key steps included an intramolecular photocyclization and a fragmentation of a bridgehead carbocation.Keywords
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