Dielectric Behavior of Aqueous Binary Mixtures of Hydrophobic Solutes
- 1 June 1992
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 65 (6) , 1716-1718
- https://doi.org/10.1246/bcsj.65.1716
Abstract
Dielectoric constant data for aqueous binary mixtures of ethylene glycol (EG), 2-methoxyethanol (ME), and 1,2-dimethoxyethane (DME) at different mole fractions and at various temperatures are reported. A decrease in dielectric constant values has been observed with the increase in solvent content of the mixture as well as the temperature in case of all the three systems. The variations in Kirkwood’s correlation factor (gK) with respect to the solvent composition in the three types of mixtures have been attributed to the short-range dipolar interactions which lead to structural changes in respective solvent mixtures.This publication has 12 references indexed in Scilit:
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