Abstract
A many-electron model is proposed to describe the electronic structure of metal-semiconductor interfaces and semiconductor heterojunctions. The model is utilized to calculate the self-consistent one-electron potential in the vicinity of the interface. This potential arises from two sources: a short-range dipole contribution due to valence-electron rearrangements at the interface relative to the corresponding vacuum surfaces, and a long-range space-charge contribution caused by band-bending effects extending thousands of angstroms from the interface.

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