The preparation, infrared spectra, and magnetic properties of some ruthenium(II), ruthenium(III), and osmium(III) complexes
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1366-1370
- https://doi.org/10.1039/j19670001366
Abstract
The preparation, i.r. spectra, and magnetic susceptibility data for complexes of the type RuCl2.4L and MCl3.3L (M = Ru, L = pyridine, β-picoline, γ-picoline; M = Os, L = pyridine or γ-picoline) and [M(L)2Cl2]XnH2O (where M = Ru, L = 2,2′-bipyridyl, X = ClO4, n= O, or X = Cl and n= 2; M = Os, L = 2,2′-bipyridyl or 1,10-phenanthroline, X = ClO4, n= 0) are reported. The i.r. spectra are discussed in terms of the possible structures of the complexes and the magnetic properties compared with the theory of a 2T2g ground state perturbed by an axial ligand field component, and spin–orbit coupling.Keywords
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