Selective functionalization of unactivated methine positions. 4-Acetyldiamantane
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 591
- https://doi.org/10.1039/c39740000591
Abstract
Irradiation of diamantane and biacetyl in methylene chloride gives in 64% yield a mixture of 4-(apical)-acetyl-(2) and 1-(medial)-acetyl-diamantane (3) in 5·5 : 1 ratio (17 : 1 after statistical correction); methylene (3-) attack is not observed.Keywords
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