On the relationship between intramolecular hydrogen abstraction by alkoxyl radicals and deshielding by the corresponding hydroxy-groups as indicated by nuclear magnetic resonance
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 13,p. 1275-1277
- https://doi.org/10.1039/p19750001275
Abstract
The 1H n.m.r. spectra of various steroids and triterpenoids and their hydroxy-derivatives have been studied. It is shown that a consideration of deshielding by hydroxy-groups can provide valuable information on the likely course of intramolecular hydrogen abstraction reactions of alkoxyl radicals.Keywords
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