Extreme symbiosis: the facile one-step synthesis of the paramagnetic cobalt(III) complex of triphenylantimony, Col3(SbPh3)2, from the reaction of triphenylantimonydiiodine with unactivated coarse grain cobalt metal powder
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 45-46
- https://doi.org/10.1039/c39940000045
Abstract
Triphenylantimony diiodine (2 equiv.) reacts with unactivated cobalt powder to yield the unexpected cobalt(III) complex Col3(SbPh3)2; this five coordinate species represents a rare example of a paramagnetic cobalt(III) complex.Keywords
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