Asymmetric hydrogenation in water by a rhodium complex of sulfonated 2,2′bis(diphenylphosphino)-1,1′-binaphthyl (binap)
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1262-1264
- https://doi.org/10.1039/c39930001262
Abstract
The synthesis of sulfonated 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (binap) is reported; a rhodium complex of this ligand is the first to perform asymmetric hydrogenation in neat water with optical yields as high as those obtained in nonaqueous solvent.Keywords
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