The mechanism of nitration of 2,3-dinitroaniline in aqueous sulphuric acid. Evidence for Bamberger's hypothesis of N-nitration followed by rearrangement
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 641
- https://doi.org/10.1039/c39720000641
Abstract
Product analyses and tracer studies involving H15NO3 show that the 6-nitration of 2,3-dinitroaniline by nitric acid in aqueous sulphuric acid occurs mainly by attack on the amino nitrogen atom followed by rearrangement.Keywords
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