The Formation of ReS2 Inorganic Fullerene-like Structures Containing Re4 Parallelogram Units and Metal−Metal Bonds
- 11 September 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 124 (39) , 11580-11581
- https://doi.org/10.1021/ja0261630
Abstract
The encapsulation of ReOx within ReS2 inorganic fullerene-like cages is described for the first time. The encapsulate was prepared by the sulfidization of both hand-milled and ball-milled samples of ReO2; partial conversion of the oxide to the sulfide was achieved with the degree of sulfidization depending on the exposure to the sulfidizing agent, H2S.Keywords
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