Stereospecific exchange of carbon monoxide in clusters of the type [Os3(CO)10X2]
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 329-330
- https://doi.org/10.1039/c39770000329
Abstract
A 13C n.m.r. study of complexes of the type [Os3(CO)10X2], where X is a three-electron donor, has shown that stereospecific exchange of labelled carbon monoxide occurs on the non-unique osmium atoms, that a subsequent exchange process distributes this label among the non-equivalent sites on the non-unique osmium atoms, and that carbonyl bridging between different types of osmium atoms does not occur.Keywords
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