Some tertiary arsine complexes of platinum and palladium
- 1 January 1974
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 27 (12) , 2557-2561
- https://doi.org/10.1071/ch9742557
Abstract
A series of square-planar complexes of platinum and palladium of the general formula MX2L2, where M is Pt or Pd, X is Cl, Br or I, and L is EtPh2As or PrPh2As, have been made. The platinum complexes (X = Cl or Br) react with the corresponding halogens to give octahedral complexes of the type PtX4L2. The dichloro complexes of platinum(II) react with carbon monoxide to give carbonyl complexes of the type trans- [PtCl(CO)L2]+. Structures have been assigned to all the compounds.Keywords
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