Fluorine‐containing polymers. II. 1, 1‐dihydroperfluoroalkyl acrylates: Preparation of monomers1
- 1 February 1955
- journal article
- research article
- Published by Wiley in Journal of Polymer Science
- Vol. 15 (80) , 515-519
- https://doi.org/10.1002/pol.1955.120158018
Abstract
Acrylate esters of seven n‐1,1‐dihydroperfluoroalkanols have been synthesized. The esters are: 1,1‐dihydroperfluoroethyl‐; 1,1‐dihydroperfluoropropyl‐; 1,1‐dihydroperfluorobutyl‐; 1,1‐dihydroperfluoropentyl‐; 1,1‐dihydroperfluorohexyl‐; 1,1‐dihydroperfluorooctyl‐; and 1,1‐dihydroperfluorodecyl acrylates. Since these alcohols were difficult to esterify using conventional procedures, acrylyl chloride or acrylic acid plus perfluoroacetic anhydride have been empolyed in this work.Keywords
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