The Lewis acid mediated reaction of carbamates with γ-oxygenated allyltin and its application to (±)-statine synthesis
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1310-1312
- https://doi.org/10.1039/c39890001310
Abstract
The Lewis acid mediated reaction of acyliminium ions (6) with γ-oxygen substituted allyltin (1c) gave the amino alcohol derivatives (7) and/or (8) in good yields; in certain cases very high diastereoselectivity was achieved and the procedure was applied to the synthesis of (±)-statine.Keywords
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