Synthesis of new fischer-type carbene complexes: characterization and reactions of titanoxycarbene–metal complexes derived from (η5-C5Me5)2Ti(C2H4) and metal carbonyls
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1145-1146
- https://doi.org/10.1039/c39860001145
Abstract
Titanoxycarbene–metal carbonyl complexes have been synthesized by the reaction of (η5-C5Me5)2Ti(C2H4) and various metal carbonyls of group 6 and 7, and characterised by spectroscopic and X-ray crystallographic techniques; at elevated temperatures, a novel cleavage of C(carbenic)–C bonds occurred to liberate ethylene and the metal carbonyl starting material.Keywords
This publication has 0 references indexed in Scilit: