Nonlinear optical properties of novel carborane–ferrocene conjugated dyads. Electron-withdrawing characteristics of carboranes
- 3 July 2002
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 12 (9) , 2701-2705
- https://doi.org/10.1039/b202236b
Abstract
The novel carborane–ferrocene conjugated dyads 1–3 and 6–8 were synthesized and their NLO properties were investigated. ortho-, meta-, and para-carboranes act as electron-withdrawing groups, and the para-carborane dyads 3 and 8 exhibited higher β values (hyperpolarizability) than the ortho- and meta-carborane analogues 1, 2, 6, 7.Keywords
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