Cycloaddition reactions of allyliron complexes: synthesis of cyclopentanoid derivatives such as (±)-sarkomycin
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 987-988
- https://doi.org/10.1039/c39840000987
Abstract
A cycloaddition reaction between dimethyl 2-cyanofumarate and (σ-3-methoxyallyl)(η5-cyclopentadineyl)dicarbonyliron has yielded a cyclopentanoid derivative which has been used in a synthesis of sarkomycin; a precursor to brefeldin A has also been prepared from the same intermediate.Keywords
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