New organic charge transfer salts (ET)4(FeCl4)2 and (ET)FeCl4 : preparation, structure, XP spectra and electrical properties
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 8 (1) , 77-80
- https://doi.org/10.1039/a706562k
Abstract
New charge transfer salts (ET)4(FeCl4)21 and (ET)FeCl42 have been prepared by the diffusion method [ET=bis(ethylenedithio)tetrathiafulvalene] and their crystal structures have been solved by X-ray analysis. The single crystals have a room temperature conductivity of 10 S cm–1 , metal-conducting behavior over the temperature range 250–300 K and 10–2 S cm–1 , semiconducting behavior over the temperature range 160–300 K, respectively. The XP spectrum of (ET)4(FeCl4)21 was also studied.Keywords
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