Calculation of core level chemical shifts for the adsorption of alkali metals on Si(111)

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Abstract
The core chemical shifts of the Si 2p electrons emitted from a Si(111) surface after the adsorption of alkali metals are studied. Initial and final state contributions are discussed. It is found that the changes in the electronic potentials are very similar to the corresponding Fermi level shifts, so only a small chemical shift, if any, will be observed.

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