Polytriazoles as Copper(I)-Stabilizing Ligands in Catalysis
Top Cited Papers
- 30 July 2004
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 6 (17) , 2853-2855
- https://doi.org/10.1021/ol0493094
Abstract
Polytriazolylamines were synthesized by the copper(I)-catalyzed ligation of azides and alkynes. The C3-symmetric derivative, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.Keywords
This publication has 9 references indexed in Scilit:
- A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal AlkynesAngewandte Chemie International Edition in English, 2002
- Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to AzidesThe Journal of Organic Chemistry, 2002
- Click Chemistry In Situ: Acetylcholinesterase as a Reaction Vessel for the Selective Assembly of a Femtomolar Inhibitor from an Array of Building BlocksAngewandte Chemie International Edition in English, 2002
- The First Water-Soluble Copper(I) Calix[6]arene Complex Presenting a Hydrophobic Ligand Binding Pocket: A Remarkable Model for Active Sites in MetalloenzymesAngewandte Chemie International Edition in English, 2002
- Asymmetric allylic oxidation of cycloalkenes using a tridentate tris(oxazoline) ligand as a chiral auxiliaryTetrahedron Letters, 2000
- Asymmetric catalytic cyclopropanation of olefins: bis-oxazoline copper complexesTetrahedron Letters, 1990
- The {Bis-2,6-[1-(2-imidazol-4-ylethylimino)ethyl]pyridine}copper(I) cation. A synthetic Cu I oxygen carrier in solution as a potential model for oxyhemocyaninJ. Chem. Soc., Dalton Trans., 1980
- A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridinesTetrahedron Letters, 1975
- Ueber symmetrische BiphenylderivateEuropean Journal of Organic Chemistry, 1904