Co2(CO)8-Catalyzed Ring-Opening Carbonylation of Cyclic Ethers Using N-Silylamines
- 1 March 1994
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 67 (3) , 879-882
- https://doi.org/10.1246/bcsj.67.879
Abstract
Co2(CO)8-catalyzed ring-opening carbonylation of oxiranes and oxetane smoothly proceeds with high regioselectivity under 1 atm of carbon monoxide at room temperature to give the corresponding β- and γ-siloxy amides in high yields, respectively. [(R3Si)2NR1R2]+[Co(CO)4]− is thought to be an active catalyst species and directs the high regioselectivity of the carbonylation.Keywords
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