Metal–oxo cluster-supported transition metal complexes: hydrothermal synthesis and characterization of [{M(phen)2}2(Mo8O26)] (M = Ni or Co)
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 983-984
- https://doi.org/10.1039/a900643e
Abstract
Two new metal–oxo supported transition metal complexes, [{M(phen)2}2(Mo8O26) (M = Ni or Co; phen = 1,10-phenanthroline) are synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the octamolybdate possesses a novel unprecedented structure and that [M(phen)2]2+ units are covalently bonded to the [Mo8O26]4– cluster.Keywords
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