New dependence of Activation Energies of Nitroesters Thermolysis and possibility of its application
- 1 February 1992
- journal article
- research article
- Published by Wiley in Propellants, Explosives, Pyrotechnics
- Vol. 17 (1) , 17-19
- https://doi.org/10.1002/prep.19920170106
Abstract
Relationship was found between activation energies E of low‐temperature non‐autocatalyzed thermolysis of the nitric acid esters, on the one hand and their oxygen balances OB100, on the other. By this relationship, molecular‐structural dependence is evidenced of values E, at the same time existence is signalized of the direct relationship between the values E and the impact sensitivity of nitroesters.Keywords
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