The formation of azoxyalkanes in reactions of some organometallic reagents with N-nitroso-O,N-dialkylhydroxylamines: the nonphotochemical synthesis of an acyclic (E)-azoxyalkane
- 15 January 1981
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 59 (2) , 264-268
- https://doi.org/10.1139/v81-043
Abstract
Azoxyalkanes were found to be regiospecifically formed in the reactions of some alkyllithium and Grignard reagents with N-nitroso-O,N-dialkylhydroxylamines. Remarkably, although (Z)-stereomers were usually produced, in one case the (E)-isomer was predominant.Keywords
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