Theory of exchange via double-occupation states in crystallineHe3
- 1 February 1975
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 11 (3) , 1045-1052
- https://doi.org/10.1103/physrevb.11.1045
Abstract
Recent theories of exchange in solid have yielded results for the exchange integral which are considerably smaller than experimental values. A new mode of exchange is suggested, based on a virtual excited state composed of a vacancy plus doubly occupied cell, which may yield somewhat larger values of . Preliminary calculations based on a variational approach are presented. Numerical results are indicative but can likely be improved with a better trial function. Arguments are given to support the claim that future computations of the exchange integral via this mechanism should give results larger than in previous theories.
Keywords
This publication has 21 references indexed in Scilit:
- Magnetic Pressure of SolidPhysical Review Letters, 1972
- Excitations in Quantum Crystals (A Survey of NMR Experiments in Solid Helium)Reviews of Modern Physics, 1971
- Cell Model of Quantum Liquids and Solids. I. Crystalline StatePhysical Review A, 1971
- Nuclear-Spin-Ordering Effects in Magnetized SolidPhysical Review Letters, 1971
- Exchange Energy in bccPhysical Review B, 1969
- Formation of Nonlocalized Vacancies in bccPhysical Review B, 1968
- Nuclear Relaxation of Solid Helium-3 in the bcc PhasePhysical Review B, 1965
- Study of the Exchange Integral of Crystallineat 0°KPhysical Review Letters, 1965
- Electron correlations in narrow energy bands. II. The degenerate band caseProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1964
- The valence bond theory of molecular structure - I. Orbital theories and the valence-bond methodProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1954