Phosphane-Free Palladium-Catalyzed Coupling Reactions: The Decisive Role of Pd Nanoparticles
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- 3 January 2000
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 39 (1) , 165-168
- https://doi.org/10.1002/(sici)1521-3773(20000103)39:1<165::aid-anie165>3.0.co;2-b
Abstract
Nanosized palladium colloids, generated in situ by reduction of PdII to Pd0 [Eq. (a)], are involved in the catalysis of phosphane‐free Heck and Suzuki reactions with simple palladium salts such as PdCl2 or Pd(OAc)2, as demonstrated by transmission electron microscopic investigations.Keywords
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