Asymmetric Induction in the Free Radical Co polymerization of Isobutyl Vinyl Ether with Maleic Anhydride inl-Menthol
- 1 July 1982
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 18 (2) , 285-297
- https://doi.org/10.1080/00222338208074425
Abstract
The radical co polymerization of isobutyl vinyl ether with maleic anhydride was carried out in the presence of l-menthol by using azobisisobutylonitrile. The resulting copolymer was found to be alternating and optically active. The overall activation energy for co polymerization was calculated to be 22.8 kcal/mol in the presence of l-menthol and 22.0 kcal/mol in the absence of l-menthol. The specific rotation of the copolymer decreased with an increase of the reaction temperature.Keywords
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