η-Cycloheptatrienyl tungsten chemistry
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1116-1117
- https://doi.org/10.1039/c39920001116
Abstract
Reduction of WCl6 with sodium amalgam in the presence of cycloheptatriene gives [W(η-C7H7)(η-C7H9)], which is a precursor to the compounds [W(η-C7H7)LX2], [W(η-C7H7)L2X], where L = tertiary phosphines or acetonitrile and X = halogen, [W(η-C7H7)(η-C5H4R)], R = H, Me, and [W(η-C7H7)(η-C9H7)].Keywords
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