Vinyl Polymerization XLVII. Polymerization of Acenaphthylene with Ziegler-Type Catalysts
- 1 January 1961
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 34 (1) , 26-28
- https://doi.org/10.1246/bcsj.34.26
Abstract
Polymerization of acenaphthylene was studied kinetically in heptane or toluene in the presence of titanium butanate-aluminum triethyl or titanium butanate-lithium aluminum hydride at 40∼95°C. Activation energy was computed as 14.3 and about 13kcal./mol. Molecular weight of the polymer obtained was 125000, while [η]Benzene30° was only 0.035 (c=g./ 100ml.).Keywords
This publication has 2 references indexed in Scilit:
- Vinyl polymerization. III. Polymerization of acenaphthyleneJournal of Polymer Science, 1955
- THE ALKYL TITANATESJournal of the American Chemical Society, 1924