Asymmetric hydroformylation of 1,2-disubstituted olefins catalysed by chiral phosphinephosphite–rhodium(I) complexes
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 395-396
- https://doi.org/10.1039/c39940000395
Abstract
Hydroformylations of internal olefins such as (E)- and (Z)-but-2-ene, (E)- and (Z)-1-phenylprop-1-ene, indene, and 1,2-dihydronaphthalene catalysed by (R,S)-binaphos–RhI complex {(R,S)-binaphos =(R)-[2-(diphenylphosphino)-1,1′-binaphthalen-2′-yl][(S)-1,1′-binaphthalen-2,2′-diyl]phosphite} or its enantiomer gave the corresponding oxoaldehydes in up to 97% enantiomeric excess, e.e.Keywords
This publication has 6 references indexed in Scilit:
- Highly enantioselective hydroformylation of olefins catalyzed by new phosphine phosphite-rhodium(I) complexesJournal of the American Chemical Society, 1993
- Platinum-catalyzed enantioselective hydroformylation with (R,R)-[bicyclo[2.2.2]octane-2,3-diylbis(methylene)]bis(5H-benzo[b]phosphindole) and related chiral ligandsOrganometallics, 1991
- Platinum-catalyzed asymmetric hydroformylation of olefins with (-)-BPPM/SnCl2-based catalyst systemsOrganometallics, 1991
- The asymmetric hydroformylation in the synthesis of pharmaceuticalsChirality, 1991
- Platinum dichloride complexes with (R,R)-[(bicyclo[2.2.2]-octane-2,3-diyl)bis(methylene)]bis[diphenylphosphine]- or bis[5H-benzo[b]phosphinindole]: new catalyst precursors for enantioselective hydroformylationTetrahedron: Asymmetry, 1990
- Synthesis of Intermediates by Rhodium‐Catalyzed HydroformylationAngewandte Chemie International Edition in English, 1980