The Crystal and Molecular Structure of Dichloro[1,3-bis(di-t-butylphosphino)propane]platinum(II) Chlorobenzene Solvate
- 1 February 1979
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 52 (2) , 390-394
- https://doi.org/10.1246/bcsj.52.390
Abstract
X-Ray crystal structure analysis of [PtCl2{(t-Bu)2P(CH2)3P(t-Bu)2}]·0.5C6H5Cl has been carried out. Crystals belong to monoclinic system: a=11.532(2), b=14.984(5), c=16.455(4) Å, β=106.96(2)°, space group P21/c with Z=4. The structure, solved by the heavy-atom method, has been refined anisotropically by least-squares procedure to R=0.056 for 5019 non-zero reflections. The coordination around the platinum atom is approximately square-planar, however, it showed a slight deviation toward the tetrahedral geometry; Pt–P=2.281(3) and 2.282(3), Pt–Cl=2.359(3) and 2.362(3) Å, P–Pt–P=99.05(9) and Cl–Pt–Cl=83.18(11)°.This publication has 2 references indexed in Scilit:
- The Crystal and Molecular Structures of Dichloro-1,2-bis(di-t-butylphosphino)ethaneplatinum(II) and its Chlorobenzene SolvateBulletin of the Chemical Society of Japan, 1976
- Crystal structure of cis-Pt[P(CH3)3]2Cl2Inorganic Chemistry, 1967