Reactions of oxygenated radicals in the gas phase. Part 3. Reactions of peracetyl radicals with alkenes
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 3,p. 360-363
- https://doi.org/10.1039/p29770000360
Abstract
Rate constants for the addition reactions of peracetic acid and peracetyl radicals with alkenes have been determined at 393 K [reactions (1) and (2)]. The alkenes studied were propene, 3-methylbut-1-ene, cis- and trans-pent-2-ene, [graphic omitted] [graphic omitted] 2-methylbut-1-ene, 2-methylbut-2-ene, and hex-1-ene. Arrhenius parameters for the reactions with 2-methylbut-2-ene have been determined as follows: log10(k1/dm3 mol–1 s–1)=(8.23 ± 0.33)–[(61 600 ± 2 420) J mol–1/2.3RT] log10(k2/dm3 mol–1 s–1)=(8.08 ± 0.12)–[(16 340 ± 910) J mol–1/2.3RT].Keywords
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