Energy distribution among the primary products of photo-dissociation
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Discussions of the Faraday Society
- Vol. 44, 208-217
- https://doi.org/10.1039/df9674400208
Abstract
Vibrational excitation of the primary products of photo-dissociation is discussed in terms of the equilibrium geometry of the excited state of the parent molecule. Approximate SCF molecular orbital calculations have been used to estimate this, and the results agree well with experiment. Vibrational excitation of halomethyl radicals, produced through photo-dissociation of the parent bromides greatly enhances their reactivity towards H-atom abstraction. New experimental data for ·CH2Cl radicals are presented and discussed.Keywords
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