Microwave optical double resonance of HNO: Rotational spectrum in Ã1A′′(100).
- 15 September 1980
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 73 (6) , 2570-2574
- https://doi.org/10.1063/1.440492
Abstract
Rotational transitions in the ?1A″(100) state of HNO were observed using the technique of microwave optical double resonance. The HNO molecule was produced in a fast flow system by the reaction of discharged oxygen with a mixture of propylene and NO. Eighteen rotational lines observed in the frequency regions of 8 to 157 GHz and rf were analyzed to give rotational constants and centrifugal distortion constants. Perturbations were found in the K‐type doubling frequencies of K−1 =1 and 2.Keywords
This publication has 25 references indexed in Scilit:
- Excitation of nitrosyl hydride by O2(1.DELTA.g)The Journal of Physical Chemistry, 1978
- Predissociation in the HNO moleculeChemical Physics Letters, 1976
- Chemiluminescent spectra of HNO and DNO in the reaction of O(3P)/O2 with NO and hydrocarbons of aldehydesChemical Physics Letters, 1973
- THE ABSORPTION SPECTRA OF HNO AND DNOCanadian Journal of Physics, 1962
- Mechanism of chemiluminescent reactions involving nitric oxide—–the H + NO reactionDiscussions of the Faraday Society, 1962
- PREDISSOCIATION IN THE HNO MOLECULECanadian Journal of Physics, 1961
- Reviews of booksTransactions of the Faraday Society, 1961
- Infrared Chemiluminescence from the Gaseous Reaction Atomic H. Plus NO; HNO in EmissionThe Journal of Chemical Physics, 1959
- Photolysis of Nitromethane and of Methyl Nitrite in an Argon Matrix; Infrared Detection of Nitroxyl, HNOThe Journal of Chemical Physics, 1958
- THE SPECTRUM AND STRUCTURE OF THE HNO MOLECULECanadian Journal of Physics, 1958