Diastereoselective Baylis–Hillman reaction of 4-oxoazetidine-2-carbaldehydes: rapid, stereocontrolled and divergent radical synthesis of highly functionalised β-lactams fused to medium rings
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 1913-1914
- https://doi.org/10.1039/a905017e
Abstract
Baylis–Hillman adducts derived from enantiopure 1-alkenyl- or alkynyl-4-oxoazetidine-2-carbaldehydes are used for the stereoselective and divergent preparation of highly functionalised β-lactams fused to medium rings through novel, chemocontrolled tandem radical addition–cyclization sequences.Keywords
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