Form factors of block copolymer micelles with spherical, ellipsoidal and cylindrical cores
Top Cited Papers
- 1 June 2000
- journal article
- research article
- Published by International Union of Crystallography (IUCr) in Journal of Applied Crystallography
- Vol. 33 (3) , 637-640
- https://doi.org/10.1107/s0021889899012248
Abstract
The form factor of a micelle model with a spherical core and Gaussian polymer chains attached to the surface has previously been calculated analytically by Pedersen and Gerstenberg [(1996). Macromolecules 29, 1363–1665.]. Non-penetration of the chains into the core region was mimicked in the analytical calculations by moving the center of mass of the chains R g away from the surface of the core, where R g is the radius of gyration of the chains. In the present work, the calculations have been extended to micelles with ellipsoidal and cylindrical cores. Non-penetration was also for these taken into account by moving the center of mass of the chains R g away from the core surface. In addition results for worm-like micelles, disk-shape micelles and micelles with a vesicle shape are given.Keywords
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