Abstract
Mesogenic 1,16-di-(1 -O - D-mannityl)-hexadeca-ne (8), 1,22-di-(1-O-D-mannityl)-docosane (9), 1-(1-O - D-mannityl)-hexadecane-16-ol (10) and 1-(1-0 - D-mannityl)-docosane-22-ol (11) are prepared from the respective α,ω-diols by glycosylation followed by glycoside reduction and deprotection.

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